Raw file colour appearance question - Lightroom 5

[mpb]

and the RAW file showed the same colouring issue as above but the jpeg didn't. This is despite both images having identical settings.

Hawthy in post 3 and Glenda above have provided the answer. Your camera processes the raw file to produce the jpeg, that is it changes things, so even though they have the same settings they will look different because of the changes made by the camera.

Even if you shoot in only raw, your camera produces a jpeg thumbnail image which is displayed on the LCD.